Residues:
a
prospect
to
be considered
to
protect the
evironment
The adaptation of Italy's
regulations to the European Union's directives is beginning to affect the
environmental field as well. The implications are many and involve some
industrial fields in an interesting way. In particular, residues having
a high content of energy, as non-conventional fuels, in cement kilns can
now be used also in Italy. Such method, furthermore, is already being widely
used in several foreign countries such as Germany, United States, Austria,
Switzerland, Belgium, Holland, Japan and France.
Cement works, in fact, have
the technology and the experience necessary to exploit the potentialities
of more organic and consistent regulations with a new project - already
being developed in some Italian works - that makes it possible to combine
safe energy saving and costs with the protection of the environment.
Waste disposal thermal process
and cement works: a possible alliance
Among the various waste disposal
methods, the thermal process is one of the most valid solutions. Because
of their repercussions on the environment, dumps are not an acceptable
solution any more and the search for sustainable alternatives in the short
term is becoming increasingly urgent.
The thermal decomposition
of molecules in incineration plants takes place through a high-temperature
(normally 900° C or over) oxidation, and is used to destroy polluting
organic and toxic and noxious compounds, to reduce the volume of the residues
and to regenerate energy.
The thermal process can
also be used in professional incinerators and during industrial processes
that involve high temperatures where the three mentioned objectives are
likely to be achieved. Among them - as stated previously - are cement works.
Cement is derived from the
fine grinding of limestone, clays, tufas, marls and schists (its chief
components). The crude mixture passes inside a reactor where heat exchanges
take place and trigger complex chemical reactions followed by a rapid cooling
down. The result of this baking process is clinker, the basic product that
is subsequently ground together with other secondary constituents to make
it more suitable for different uses.
The baking phase is the
heart of the production of cement. Kilns reach a temperature equal to 1,450°C
and absorb between 90 and 100% of the energy consumed as a whole by the
entire process of the cement production.
This consumption, that considerably
affects costs, is the object of a particular attention and of initiatives
aimed at its reduction. Cement works, then, are strongly interested to
look for alternative energy sources.
The 94/76 EU directive on
dangerous waste incineration equated the role of professional incinerators
to that of industrial plants burning residues as alternative fuel. As mentioned
previously, in fact, when producing cement, the baking phase of clinker
requires very high temperatures for a long time in a highly oxidising atmosphere
of the gases. This creates even more favourable conditions than those existing
in incinerators. In this case the law limits the caloric supply of residues
to 40% of the total requirements of the plant's primary energy. During
the cement production process, the reuse of residues can have two different
aims:
- residues to be re-used
in the crude mixture of the kiln firing to bake clinker (for example purple
ore, iron oxides, exhausted sands and earth from foundries and so on);
- residues to be used
as secondary constituents of cements (such as blast furnace slags, flying
cinders, chemical gypsum, exhausted sands and earth from foundries and
so on).
What advantages?
The thermal process used
in cement kilns involves a large number of advantages both in terms of
saving (economical and of raw materials) and of protection of the environment,
for general applications and for professional incinerators in particular.
First of all energy is almost
completely regenerated: the thermal energy obtained from the residues replaces
the one saved in conventional fuels with a ratio of 1:1. This value is
far less meaningful in incinerators and sometimes is even equal to zero
for old plants.
As far as the environmental
aspect is concerned, the quantities of the kilns' emissions remain unchanged,
but the CO2 concentration is lower. The emissions of a special incineration
furnace, furthermore, are eliminated.
Using the quantities of
residues allowed by the law as much as possible (equal to 40% of the total
necessary energy), it would be possible to save 1,700.000 t/a of pit coal
(a natural resource that cannot be renewed).
Re-using cement kilns does
not involve the formation of solid residues, dross or liquids and disposal-related
problems that conventional kilns normally have to cope with.
Cement-producing plants
are submitted to constant controls that make the reuse process safe in
terms of atmospheric pollution prevention.
Furthermore, it must be
noted that re-using residues in cement kilns does not change the cement
characteristics that is perfectly sustainable with the environment and
not harmful for human health.
The interests of cement
manufacturers to enhance the use of cement kilns for waste disposal is
also supported by other observations: the uniform distribution of cement
works across the country, the amount of investments to comply cement plants'
kilns with the thermal process of the residues (that are considerable although
always lower than those necessary to build new incinerators), the existing
presence of plants to destroy dusts, in fact, make cement works potentially
interesting to tackle the problem of waste disposal and its relationship
with the environment.
The effects on the environment
are considerable.
In the first place, risks
to pollute the earth and the waters are not expected because the reuse
(unlike in professional incinerators) does not entail the production of
solid and liquid residues. Kilns are provided with plants that eliminate
dusts suspended in emitted gases, the concentration of sulphur oxides in
emitted gases is reduced thanks to some chemical and physical characteristics
of the process. Normally, there also is a reduction of the percentage of
nitric oxides in the emitted gases, dangerous organic compounds are almost
completely destroyed, and there are no considerable increases of the emitted
metals.
Among the fuels of the future
we can include (with further improvement of the separation process and
the elimination of non-compatible components) urban solid waste and PDF
(package-derived fuel) that is obtained from the waste of plastic materials
with a high energy content.
According to the information
reported, the cement industry can now considerably contribute to reuse
high-energy residues in order to better preserve natural resources that
are not renewable and the environment itself.
The regeneration of energy
carried out in cement kilns, in fact, is a globally favourable operation
as far as ecology and the environment are concerned and, as shown by its
application in technologically advanced and environmentalist countries
in Europe, United States and Japan, does not have negative health repercussions
on people and on the plants' workers.
Aware of the fact that the
protection of the environment is a responsibility that cannot be postponed
for the industrial sector as well, cement manufacturers can and intend
to contribute considerably with their experiences and know-how to a consistent
growth with the most advanced regulations and choices at a world level. |